Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation     

Pasquale Crea  Concetta De Stefano  Demetrio Milea  Silvio Sammartano   《Marine Chemistry》2008,112(3-4):142-148

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).  相似文献   

Effect of parallel electric field on electrostatic ion-cyclotron instability in anisotropic plasma in the presence of ion beam and general distribution function—Particle aspect analysis     

Ruchi Mishra 《Planetary and Space Science》2006,54(2):188-199

Dispersion relation, resonant energy transferred, growth rate and marginal instability criteria for the electrostatic ion-cyclotron wave with general loss-cone distribution in low-β anisotropic, homogeneous plasma in the auroral acceleration region are discussed by investigating the trajectories of the charged particles. Effects of the parallel electric field, ion beam velocity, steepness of the loss-cone distribution and temperature anisotropy on resonant energy transferred and growth rate of the instability are discussed. It is found that the effect of the parallel electric field is to stabilize the wave and enhance the transverse acceleration of ions whereas the effect of steepness of loss-cone, ion beam velocity and the temperature anisotropy is to enhance the growth rate and decrease the transverse acceleration of ions. The steepness of the loss-cone also introduces a peak in the growth rate which shifts towards the lower side of the perpendicular wave number with the increasing steepness of the loss-cone.  相似文献   

Sheath effects on DEMETER ion drift measurements     

Richard Marchand  Nelson Knutson 《Planetary and Space Science》2010,58(10):1365-1373

The “Instrument d’Analyse du Plasma” on DEMETER includes an ion drift meter used to measure the direction of the incoming ram plasma ( [Berthelier et al., 2006a] and [Berthelier et al., 2006b]). Given the velocity of the satellite, and expected flow velocities of plasma along DEMETER's orbit, it is estimated that at mid latitudes, the direction of incident plasma as measured by IAP should be within approximately 2° of the ram direction. Yet, significantly larger angular deviations are measured routinely. An important assumption made in the interpretation of onboard instruments, such as IAP, is that neither the spacecraft nor the instrument significantly perturb the plasma that is being measured. In view of the large observed angular deviations, this paper examines the possible effect of the electrostatic sheath surrounding IAP. This is done with the 3D PIC simulation code PTetra. The model uses a full 3D particle in cell code with unstructured tetrahedral mesh capable of accurately representing the satellite geometry. The mesh is also adaptive so as to provide a fine spatial resolution in the vicinity of the particle sensor where it is needed, and a coarse resolution in regions where plasma parameters vary over a longer scale length. Calculation results show that while particle deflection associated with the electrostatic sheath near IAP can account for appreciable angular deflections for representative ionospheric plasmas, they are typically smaller than the ones observed. Additionally, the model is unable to reproduce the latitudinal dependence of the observed large deflection angles. It is concluded that sheath effects may cause appreciable distortions on the IAP type of ion flow meter instruments, and on other particle sensors in general. The larger observed deviations and their latitudinal dependence, however, must be attributable to other physical processes not accounted for in the model.  相似文献   

随机介质模型的一种构造方法   总被引：1，自引：0，他引：1  

王金山  陈可洋  吴清岭  杨微 《物探与化探》2010,34(2)

为更好地描述真实的地下介质特点,提出了一种局部随机位置或固定位置任意形状截取法并结合多尺度建模技术来共同构造随机介质模型的新方法。从现有的随机建模理论出发,在有效的建模区域内产生或者给定局部扰动位置,以此作为局部扰动分布区的中心点,引入局部扰动半径R和局部随机或给定扰动角度θ两个模型特征量,采用局部位置任意形状截取法并充填各种随机介质,从而构造各种不同的随机介质模型。给出了局部位置任意形状截取法的基本步骤和应用实例。  相似文献   

The construction and development of SHRIMP I: An historical outline     

John J. Foster 《Precambrian Research》2010

In 1973 Bill Compston advocated the building of an ion microprobe at the Research School of Earth Sciences (RSES) at the Australian National University (ANU). The commercial ion probes available at this time were too small to have sufficient sensitivity for trace element analysis and too low in mass resolution to avoid molecular interferences. The project commenced in 1974 with the appointment of a former ANU PhD student Steve Clement who had expertise in beam transport theory. To achieve high sensitivity and high mass resolution, beam transport theory indicated that a much larger magnet than in any commercially available mass spectrometer would be required. Clement chose an ion optical design, by Professor Matsuda of Osaka University in 1974, which had the required combination of high mass resolution and high transmission. Clement's job was to produce the detailed scientific designs and machine drawings for the new instrument as well as testing the completed instrument. Clement coined the term SHRIMP-Sensitive High Resolution Ion MicroProbe. By the end of 1977 nearly all the components had been manufactured and the big electromagnet had been successfully tested. In the following year the secondary mass analyzer was assembled and tested using a thermal ionization source and showed great promise with flat-topped peaks at 5000 resolution and 50% transmission with 50 V energy spread. At this stage the machine had far exceeded the specifications for the available commercial ion probes. Continued development during 1981 to the point where the original design specifications were fully realized was time consuming since learning how to use the entirely novel instrument was no simple task; no one else had an instrument like SHRIMP. The application of the instrument to zircon U–Pb geochronology established the necessary operating conditions for measuring Pb isotopic compositions and the elemental ratios Pb/U and U/Zr from 20 μm diameter spots on single zircon grains. Application of this in the early 1980s started a revolution in Precambrian geology by the ability to produce rapidly accurate and precise age determinations on structurally complex zircon samples.  相似文献   

中国西部地区方沸石胶结相与碎屑岩次生优质储集层形成机制   总被引：2，自引：0，他引：2       下载免费PDF全文

孙玉善  刘新年  张艳秋  董尉凯  徐彦龙  师桂霞  林艳波  李安琼 《古地理学报》2014,16(4):517-526

含油气盆地碎屑岩次生优质储集层的发育,除了与广泛发育的方解石胶结相有关外,在中国西部还有一类与沸石族自生矿物胶结的成岩相有关,其中以溶蚀方沸石胶结相形成的次生优质储集层与油气聚集成藏又有十分密切的关联。经实例分析:与自生方沸石胶结有关的成岩相主要受控于扇(辫状河)三角洲前缘相带、火山岩物源和成岩早期的碱性环境;次生优质储集层的形成在时间上主要处于成岩中期A阶段,在空间上受控于邻近的烃源岩、圈闭和输导体的沟通。方沸石矿物在物理性质上具有抗压易溶(有机酸)作用,较其他常见的自生矿物(胶结物)相对优越,就方沸石易于溶蚀的特点而言是较为理想的自生矿物(胶结物)。其溶蚀对孔隙度的贡献率在50％～75％之间,发育几率占绝对优势。所以,在方沸石发育的相带中寻找以粒间溶蚀孔为主的优质储集层,具有可靠的操作性和现实性。  相似文献   

Chemical Analysis of Water and the Resource of Br,K Prospects of Oilfield Brines from Ordovician and Carboniferous in Tarim,China     

SU Kui  ZHENG Mianping  CHEN Lixin  LI Baohu  CHEN Yongquan 《《地质学报》英文版》2014,88(Z1):250-250

正China is lack of bromine and potassium seriously.Oilfield brines is the headline goal of bromine and potassium resources exploration.Applicants grab 24oilfield brines samples from various wells of Ordovician  相似文献   

拉果错盐湖卤水蒸发过程中Li⁺富集行为的分子动力学模拟          下载免费PDF全文

刘鑫  马艳芳  张志宏  付振海 《盐湖研究》2022,30(4):61-71

采用分子动力学模拟,研究了西藏拉果错盐湖卤水中阴、阳离子以及水分子间的相互作用行为。以盐湖卤水等温蒸发过程中粒子浓度变化的四个阶段为研究对象,分别计算了不同体系的扩散系数、配位数、均方位移和径向分布函数。计算结果表明,液相浓度越低时,H₂O分子对各离子之间的相互作用有抑制作用,液相中离子浓度越高时,SO₄2-易与CO₃2-竞争Li⁺形成离子对,从而影响盐湖卤水中Li⁺的富集。本文研究结果对盐湖卤水中Li⁺的迁移行为作出了机理解释,为盐湖卤水提锂的发展奠定了理论基础。  相似文献   

封闭系统中CaCO_3在天然水中溶解或沉淀的水化学后果     

钱会  李雨新 《地球科学与环境学报》1994,(2)

文章在计算水溶液化学组份平衡分布及其ｐＨ值的基础上，分析和讨论了封闭系统中ＣａＣＯ３溶解或沉淀所引起的水化学后果，并依据计算数据和借助作图的办法得出了如下结论，即ＣａＣＯ３溶解会使水溶液ｐＨ值增大，Ｈ２ＣＯ３含量减少；相反，ＣａＣＯ３沉淀会使水溶液ｐＨ值减小，Ｈ２ＣＯ３含量增多。  相似文献   

An Evaluation of Phase Behaviors of the Oil-Gas-Water System in the Displacement of Crude Oil with CO₂     

ZHANG Angang  FAN Zifei  HE Jun 《《地质学报》英文版》2023,97(2):573-580

CO₂ dissolution into an aqueous phase and water evaporation into a gaseous phase takes place during CO₂ injection into an oil reservoir. This study aims to evaluate the phase behaviors of the oil-gas-water system in the displacement of crude oil by CO₂. The composition of the JL oilfield in the northeast of China is taken as an example. The flash calculation of the oil-gas-water system was performed, based on the method presented by Li and Nghiem. The research re...  相似文献